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1 article(s) from Hensel, Susanne

Second generation silver(I)-mediated imidazole base pairs

Susanne Hensel,
Nicole Megger,
Kristina Schweizer and
Jens Müller

Beilstein J. Org. Chem. 2014, 10, 2139–2144, doi:10.3762/bjoc.10.221

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Scheme 1: Schematic representation of an imidazole–Ag(I)–imidazole base pair (top) and a thyminate–Hg(II)–thy...

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Figure 1: Different views of a DNA duplex comprising three neighbouring imidazole–Ag(I)–imidazole base pairs....

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Scheme 2: Schematic representation of silver(I)-mediated imidazole homo base pairs involving 2-methylimidazol...

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Scheme 3: Synthesis of methylimidazole-based nucleosides and their corresponding phosphoramidites required fo...

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Scheme 4: Oligonucleotide sequences under investigation (X = 2-methylimidazole 2a or 4-methylimidazole 2b).

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Figure 2: Melting curves based on normalized UV absorbance at 260 nm of a) duplex I with X = 4-methylimidazol...

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Figure 3: CD spectra of a) duplex I with X = 4-methylimidazole and b) duplex II with X = 2-methylimidazole in...

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Published 09 Sep 2014

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